Fakulteta za industrijski inženiring Novo mesto Predmet: Course title: Faculty for Industrial Engineering Novo mesto UČNI NAČRT PREDMETA / COURSE SYLLABUS KEMIJA CHEMISTRY Študijski program Study programme and level Letnik Academic year prvi first Študijska smer Study field INŢENIRING IN VOZILA ENGINEERING AND VEHICLES - Vrsta predmeta / Course type Obvezni / Obligatory Univerzitetna koda predmeta / University course code: VS - 3 Predavanja Lectures Seminar Seminar Sem. vaje Tutorial 45 - 5 Nosilec predmeta / Lecturer: Jeziki / Languages: Lab. vaje Laboratory work 25 Teren. vaje Field work - Samost. delo Individ. work 75 Semester Semester prvi first ECTS 5 Red. prof. dr. Miha JAPELJ/Prof. Miha JAPELJ, Dr. Sci. Izr. Prof. dr. Darja RUDAN TASIČ/Assoc. Prof. Darja RUDAN TASIČ, Dr. Sci. Predavanja / slovenski Lectures: slovenian Vaje / Tutorial: slovenski slovenian Pogoji za vključitev v delo oz. za opravljanje študijskih obveznosti: pogoj za vključitev v delo je vpis v prvi letnik študija znanje vsaj enega tujega jezika (angleščina!) opravljen kolokvij iz vaj je pogoj za pristop h končnemu izpitu Prerequisits: enrolment in the first year of studies knowledge of at least one foreign language (English!) passed colloquium from lab work is needed to enter the final exam Vsebina: Predavanja: Osnovni kemijski pojmi in stehiometrija. Struktura molekul in kemijska vez. Energijske spremembe v kemijskih sistemih. Raztopine. Kisline, baze, soli. Kemijske reakcije (nevtralizacija, hidroliza, redoks reakcije) in 1 Content (Syllabus outline): Lectures: Basic chemical terminology and stoichiometry. Structure of molecules and chemical bonds. Energy changes in chemical systems. Solutions. Acids, bases, salts. Chemical reactions (neutralization, hydrolysis, redox reactions) and their practical use. Electrochemistry. Fakulteta za industrijski inženiring Novo mesto praktična uporaba. Elektrokemija. Korozija. Baterije, akumulatorji, gorivni členi. Osnove kemijske kinetike. Aplikacije v industriji. Kovine, pregled lastnosti in uporabe nekaterih. Organska kemija in organska kemijska tehnologija. Zgradba organskih spojin. Ogljikovodiki, alkoholi, aldehidi, ketoni, kisline, etri, estri, organske dušikove spojine, heterociklične spojine. Pomen kemijskih tehnologij in njih sodobni razvoj. Premog, nafta, kreking, reforming, motorna goriva. Zelena kemija in tehnologija, biogoriva, okolje. Polimeri. Pesticidi. Kemija in zdravila. Vaje: Priprava raztopin. Merjenje gostote tekočih goriv. Določanje koncentracije kislin oz. baz, merjenje vrednosti pH. Priprava galvanskih členov, merjenje potenciala. Merjenje električne prevodnosti raztopin elektrolitov. Določanje specifične toplote kovin. Določanje trdote vode. Destilacija tekoče zmesi. Kemijska karakterizacija biodizla. Sinteza acetilsalicilne kisline. Faculty for Industrial Engineering Novo mesto Corrosion. Batteries, accumulators, fuel cells. Fundamentals of chemical kinetics. Applications in industry. Metals, review of properties and employability of some of them. Organic chemistry and organic chemical technology. Structure of organic compounds. Carbohydrates, alcohols, aldehydes, ketones, ethers, esters, nitrogen organic compounds, heterocyclic compounds. The importance of chemical technologies and their recent development. Coal, crude oil, cracking, reforming, motor fuels. Green chemistry and technology, biofueles, environment. Polymers. Pesticides, Chemistry and drugs. Laboratory practice: Solutions preparation. Measurement of fuel density. Determination of concentration of acids and bases, pH measurements. Preparing of galvanic cells, measurement of electric potential. Conductivity measurements of electrolyte solutions. Determination of specific heat of metals. Measurement of water hardness. Distillation of liquid mixture. Chemical characterization of bio diesel. Synthesis of acetylsalicylic acid. Temeljni literatura in viri / Readings: Obvezna/Obligatory Atkins, P. W., Clugston, M. J., Frazer, mM. J., Jones, R. A. Y., 1995. KEMIJA-zakonitosti in uporaba. Tehniška zaloţba Slovenije. Ljubljana, 543 s. Tišler M. 1982. ORGANSKA KEMIJA, DZS. Ljubljana, 483 s. Rudan Tasič D., Klofutar C. 2011(V pripravi). VAJE IZ KEMIJE. Fakulteta za industrijski inţeniring. Novo mesto. Priporočljiva/Recommended Čeh, B. 2005. SPLOŠNA IN ANORGANSKA KEMIJA-zbirka pojmov, vprašanj in nalog z odgovori. Univerza v Ljubljani, Fakulteta za kemijo in kemijsko tehnologijo. Ljubljana, 240 s. Austin, George T. 1985. SHREVE'S CHEMICAL PROSESS INDUSTRIES, INTERNATIONAL STUDENTS EDITION, McGraw-Hill, 859 p. Japelj M.1992. RASTLINSKA ZAŠČITNA SREDSTVA, Skripta, Univerza v Ljubljani,36 s. Solomons, G., Fryhle, C. B., 2000. Organic Chemistry, seventh edition. John Wiley and Sons, Inc. New York, p 1258 s. Cilji in kompetence: Cilji: Predmet daje študentom teoretične osnove mnogih naravnih pojavov in razlago zakonitosti, na katerih je osnovana kemijska in fizikalno kemijska klasifikacija materije. Predstavljena je povezava med zgradbo snovi in njenim vplivom na kemijske ter fizikalne lastnosti snovi. V okviru predmeta slušatelj spozna nekatere teoretične in 2 Objectives and competences: Objectives: The course gives students theoretical basis of several natural phenomena and explanation of principles, on which chemical and physical classification of matter is established. Correlation between substance structure and its effect on chemical and physical properties of the substance is presented. During the course students get to know some theoretical and practical experimental Fakulteta za industrijski inženiring Novo mesto Faculty for Industrial Engineering Novo mesto eksperimentalne metode, ki so osnova pri reševanju tehnoloških problemov, zlasti v povezavi z njihovo bodočo dejavnostjo v industriji, obrti in storitvah. methods that are the basis of solving technological problems, especially in connection with their future industry, trade and service activities. Kompetence: Sposobnost uporabe pridobljenega teoretičnega znanja v praksi Usposobljenost za ocenjevanje in vrednotenje merilnih rezultatov Usposobljenost za načrtovanje in spremljanje tehnoloških procesov Competences: Ability of using of the gained theoretical knowledge in practical work Qualification for estimation and evaluation of measuring results Qualification for planning and monitoring of technological processes Predvideni študijski rezultati: Intended learning outcomes: Znanje in razumevanje: Knowledge and understanding: Študent/študentka: Student: osveţi in nadgradi znanje iz kemije z niţjih freshens up and upgrades his/her knowledge in nivojev šolanja chemistry from lower school levels poglobi razumevanje kemijskih konceptov deepens his/her understanding of chemical concepts razume povezavo med zgradbo snovi in njenimi understands correlation between structure and their fizikalno kemijskimi lastnostmi physical-chemical properties of substances spozna nekatere teoretične in eksperimentalne comes to know several theoretical and experimental metode, ki so osnova pri pripravi, spremljanju, methods that are the basis of preparing, monitoring, vodenju in razumevanju določenih tehnoloških managing and understanding of different postopkov. technological procedures spozna pomen raziskav in razvoja pri uveljavljanju comes to know the importance of research and novih tehnologij. development in implementations of the new technologies Metode poučevanja in učenja: sistematična predavanja individualno in skupinsko delo s študenti v obliki konzultacij eksperimentalno delo v ustrezno fizikalno kemijsko opremljenem laboratoriju abstraktna konceptualizacija Načini ocenjevanja: Način (pisni izpit, ustno izpraševanje, naloge, projekt) Izpit: pisni izpit ustni izpit Learning and teaching methods: systematic lectures individual and group work with students such as consultations experimental work in adequately physco-chemically equipped laboratory abstract conceptualization Delež (v %) / Assessment: Weight (in %) Type (written and oral examination,coursework, project): 70 % 30 % Seminar (po ţelji) lahko doprinese h 3 Examination: written examination oral examination Fakulteta za industrijski inženiring Novo mesto končni oceni izpita do 10 %. Vaje: kolokvij iz vaj praktično delo in poročila iz vaj Faculty for Industrial Engineering Novo mesto Seminar (if desired) can contribute to the final mark of exam up to 10 % 70 % 30 % Experimental work: colloquium from lab work coursework report Reference nosilca / Lecturer's references: Prof. dr. Miha Japelj: JAPELJ, Miha, POKORNY, Miroslav. Antibiotiki včeraj, danes, jutri, Raziskovalec, 1991, 21 (1), 26-41. JAPELJ, Miha, VITEZIĆ, Natalija. Important Industrial Synthesis of Betalactam Antibiotics, Rad Jugoslovenske akademije, 1983, 2, str. 103-116, ilustr. [COBISS.SI-ID 21898245]. JAPELJ, Miha, VITEZIĆ, Natalija. Some Aspects in the Industrial Synthesis of ß-Lactam Antibiotics, Vestn. Slov. Kem. Društva, 1990, 459-480. LEBAN, Ivan, GOLIČ, Ljubo, JAPELJ, Miha. Crystal and Molecular Structure of Qinghaosu, Acta Pharm. Jugosl., 1988, 71-77. LIKAR, Miha, JAPELJ, Miha. Animal Carneas as Tools for the Testing of Antiviral Compounds, Annals of the New York Academy of Science, 1977, 182-189. MERSLAVIČ, Mario, ZUPET, Pavle, FLEGO, Vesna, JAPELJ, Miha, STANOVNIK, Branko, CIRNSKI, Janja. Postopek za pripravo derivatov L-alanil-L-prolina, Jugoslovanski patent, 1355, 1988. OKLOBDŢIJA, Milan, JAPELJ, Miha, OSTROVERŠNIK, Srečko, JERMAN, Peter. Postopek za pripravo 7-kloro-2,3-hidro-1-metil-5-fenil-1H-1,4-benzodiazepina, Avstralski patent, 44945, 1972. JAPELJ, Miha, RASPOR, Peter, GASPARIČ, Aleš, KOGEJ, Stane. Kritične tehnologije in tehnološko predvidevanje na področjih kemije in biotehnologije v slovenski farmacevtski industriji, Vizija in strategija razvoja kemijske industrije v Sloveniji, FKKT, Maribor, 2000. POKORNY, Miroslav, JAPELJ, Miha, FILIPOVIĆ, Branko, ČADEŢ, Janez. Proizvodnja antibiotikov in drugi sekundarnih metabolitov, Biotehnologija, 1992, 397-417. JAPELJ, Miha, STANOVNIK, Branko, TIŠLER Miha. Syntheses in the pyridazine series. 30, Protonation and quaternization studies on imidazo[1, 2-b]pyridazines and s-triazolo[4,3-b]pyridazines. J. heterocycl. chem., August 1969, vol. 6, str. 559-566. [COBISS.SI-ID 19731205]. JAPELJ, Miha, STANOVNIK, Branko, TIŠLER Miha. Synthesen in der Pyridazin-Reihe. Mitt. 26, Synthese und homolytische Methylierung von s-Triazolo[4,3-b]pyridazinen. Monatsh. Chem., 1969, vol. 100, str. 671-680, graf. prikazi. [COBISS.SI-ID 19730437]. LIKAR, Miha, JAPELJ, Miha. Animal corneas as tools for the testing of antiviral compounds. Ann. N.Y. Acad. Sci., 1977, vol. 284, str. 182-189, ilustr. [COBISS.SI-ID 21926917] Prof. dr. Darja Rudan Tasič: RUDAN TASIČ, Darja, KLOFUTAR, Cveto. Calorimetric studies of the neutralization of polygalacturonic acid. Thermochim. acta. [Print ed.], 1994, 246, str. 25-32. [COBISS.SI-ID 1023352] RUDAN TASIČ, Darja, KLOFUTAR, Cveto. Osmotic coefficients and solvation thermodynamics of aqueous solutions of some lower poly(ethylene glycol)s at different temperatures. J. mol. liq.. [Print ed.], 2003, vol. 103/104, str. 187-200. [COBISS.SI-ID 2730872] RUDAN TASIČ, Darja, KLOFUTAR, Cveto. Volumetric properties of aqueous solutions of some cyclohexylsulfamates at 25.0 °C. Food chem.. [Print ed.], 2004, vol. 84, no. 3, str. 351-357. [COBISS.SI-ID 2825080] RUDAN TASIČ, Darja, KLOFUTAR, Cveto. Apparent specific volume and apparent specific refraction of some poly (oxyethylene) glycols in 1,4-dioxane and benzene solutions at 298.15 K. Monatsh. Chem., 2004, vol. 135, str. 1209-1224. [COBISS.SI-ID 3008120] RUDAN TASIČ, Darja, KLOFUTAR, Cveto. Apparent specific polarization and dipole moment of some 4 Fakulteta za industrijski inženiring Novo mesto Faculty for Industrial Engineering Novo mesto poly(oxyethylene) glycols in 1,4-dioxane and benzene solutions at 298.15 K. Monatsh. Chem., 2005, vol. 136, str. 1171-1182. [COBISS.SI-ID 3091832] RUDAN TASIČ, Darja, KLOFUTAR, Cveto, BEŠTER-ROGAČ, Marija. The electric conductivities of aqueous solutions of rubidium and cesium cyclohexylsulfamates, potassium acesulfame and sodium saccharin. Acta chim. slov.. [Tiskana izd.], 2006, vol. 53, no. 3, str. 324-330, Graf. prikazi. http://acta.chem-soc.si/53/533-324.pdf. [COBISS.SI-ID 27955461] KLOFUTAR, Cveto, HORVAT, Jaka, RUDAN TASIČ, Darja. Apparent molar volume and apparent molar expansibility of rubidium, cesium, and ammonium cyclohexylsulfamate in aqueous solution. Monatsh. Chem., 2006, vol. 137, str. 1151-1162. [COBISS.SI-ID 3230840] LEBAN, Ivan, RUDAN TASIČ, Darja, LAH, Nina, KLOFUTAR, Cveto. Structures of artificial sweeteners : cyclamic acid and sodium cyclamate with other cyclamates. Acta crystallogr., B Struct. sci., 2007, vol. B63, no. 3, str. 418-425, ilustr. [COBISS.SI-ID 28619269] RUDAN TASIČ, Darja, KLOFUTAR, Cveto. Fizikalnokemijske metode v živilstvu. Ljubljana: Biotehniška fakulteta, Oddelek za ţivilstvo, 2007. VI, 376 str., ilustr. ISBN 978-961-6333-56-6. [COBISS.SI-ID 233342464] HORVAT, Jaka, BEŠTER-ROGAČ, Marija, KLOFUTAR, Cveto, RUDAN TASIČ, Darja. Viscosity of aqueous solutions of lithium, sodium, potassium, rubidium and caesium cyclohexylsulfamates from 293.15 to 323.15 K. J. solution chem., 2008, vol. 37, no. 9, str. 1329-1342. [COBISS.SI-ID 29743365] RUDAN TASIČ, Darja, POKLAR ULRIH, Nataša, KLOFUTAR, Cveto. Osmotic coefficients of aqueous solutions of potassium acesulfame, sodium saccharin, and ammonium and tetramethylammonium cyclohexylsulfamates at the freezing point of solutions. Monatsh. Chem., 2010, vol. 141, no. 2, str. 149-155, doi: 10.1007/s00706-009-0237-0. [COBISS.SI-ID 3741048] RUDAN TASIČ, Darja, KLOFUTAR, Cveto, BEŠTER-ROGAČ, Marija. Dipole moment and self-association of acesulfame and saccharin in 1,4-dioxane solution at 298.15 K. Monatsh. Chem., 2011, vol. 142, no. 1, str. 19-24, doi: 10.1007/s00706-010-0411-4. [COBISS.SI-ID 34659333] 5