CODE-9 PAPER-1 Time: 3 Hours P1-15-9 Maximum Marks: 264 READ THE INSTRUCTIONS CAREFULLY GENERAL: 1. This sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so. 2. The question paper CODE is printed on the left hand top corner of this sheet and the right hand top corner of the back cover of this booklet. 3. Use the Optical Response Sheet (ORS) provided separately for answering the questions. 4. The ORS CODE is printed on its left part as well as the right part. Ensure that both these codes are identical and same as that on the question paper booklet. If not, contact the invigilator. 5. Blank spaces are provided within this booklet for rough work. 6. Write your name and roll number in the space provided on the back cover of this booklet. 7. After breaking the seal of the booklet, verify that the booklet contains 32 pages and that all the 60 questions along with the options are legible. QUESTION PAPER FORMATAND MARKING SCHEME: 8. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists of three sections. 9. Carefully read the instructions given at the beginning of each section. 10. In Section 1 contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both inclusive). Marking scheme: + 4 for correct answer, 0 if not attempted and –2 in all other cases. 11. In Section 2 contains 10 multiple choice questions with one or more than one correct option. Marking scheme: + 4 for correct answer, 0 if not attempted and –2 in all other cases. 12. In Section 3 contains 2 “match the following” type questions and you will have to match entries in Column I with the entries in column II. Marking scheme: for each entry in column I, + 2 for correct answer, 0 if not attempted and –1 in all other cases. OPTICAL RESPONSE SHEET: 13. The ORS consists of an original (top sheet) and its carbon-less copy (bottom sheet). 14. Darken the appropriate bubbles on the original by applying sufficient pressure. This will leave an impression at the corresponding place on the carbon-less copy. 15. The original is machine-gradable and will be collected by the invigilator at the end of the examination. 16. You will be allowed to take away the carbon-less copy at the end of the examination. 17. Do not tamper with or multilate the ORS. 18. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each digit of your roll number. DARKENING THE BUBBLES ON THE ORS: 19. Use a BLACK BALL POINT PEN to darken the bubbles in the upper sheet. 20. Darken the bubble COMPLETELY. 21. Darken the bubbles ONLY if you are sure of the answer. 22. The correct way of darkening a bubble is as shown her: 23. The is NO way to erase or “un-darken” a darkened bubble. 24. The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are evaluated. C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org -1 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 PART I : PHYSICS SECTION 1 (Maximum Marks: 32) This section contains EIGHT questions The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive For each question, darken the bubble corresponding to the correct integer in the ORS Marking scheme: + 4 If the bubble corresponding to the answer is darkened 0 in all other cases 1. A nuclear power plant supplying electrical power to a village uses a radioactive material of half life T years as the fuel. The amount of fuel at the beginning is such that the total power requirement of the village is 12.5% of the electrical power available from the plant at that time. If the plant is able to meet the total power needs of the village for a maximum period of nT years, then the value of n is Sol: [3] If initially x is amount of fuel, then energy is E. Energy required = 1 E 8 x Tx Tx Tx 3T 2 4 8 n=3 2. A Young’s double slit interference arrangement with slits S 1 and S 2 is immersed in water S1 (refractive index = 4/3) as shown in the figure. The positions of maxima on the surface of water 2 2 2 2 d x 2 are given by x = p m – d , where is the air d wavelength of light in air (refractive index = 1), S2 2d is the separation between the slits and m is water an integer. The value of p is d 2 x2 c Sol: [3] t t x2 = p2m22 – d2 4 d 2 x2 3 c 4 1 t t t 1 (d 2 x 2 )1/2 3 c t 1 2 (d x 2 )1/2 3c 2 2 x t T 9m22 = d2 + x2 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org -2 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) f 2 ( d x 2 )1/2 3c 3mc = f(d2 + x2)1/2 x JEE-Advanced-2015 x2 = 9m22 – d2 3mc ( d 2 x 2 )1/ 2 f P=3 3. Consider the concave mirror and a convex lens (refractive index = 1.5) of focal length 10 cm each, separated by a distance of 50 cm in air (refractive index = 1) as shown in the figure. llll llll llll lllllll lllll llllllllllllllllllllllllll An object is placed at a distance of 15 cm from the mirror. Its erect image formed by this combination has magnification M1. When the set-up is kept in a medium of refractive index 7/6, the magnification becomes M2. The 15 cm M2 magnitude M is 1 50 cm Sol: [7] 1 1 1 v u f m v 30 2 u 15 1 1 1 v 15 10 1 1 1 3 2 1 v = –30 v 10 15 30 30 For lens u = 2f = 20. So the final image is at 2f ahead of lens. M1 = 2 ....(i) 1 3 6 1 1 1 f 2 1 R1 R2 1 1 1 1 10 2 R1 R2 10 4 f 14 1 3 1 1 1 10 2 R1 R2 M2 = m1 × m2 = 2 × 140 = 2 × 7 = 14 20 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org -3 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 70 4 f 1 4 1 87 1 v 70 20 140 40 ....(ii) 1 1 4 v 20 70 M2 = 14 M2 So M 7 1 4. z An infinitely long uniform line charge distribution of charge per unit length lies parallel to the y-axis in 3 a (see figure). If the 2 magnitude of the flux of the electric field through the rectangular surface ABCD lying in the x-y plane with the y-z plane at z y O A B z 1 Sol: [6] Q 0 C a L its centre at the origin is n (0 = permittivity of o free space), then the value of n is L D L L 0 L 360º ––––––– 0 1 L 60º –––––––– 6 0 n=6 5. Consider a hydrogen atom with its electron in the nth orbital. An electromagnetic radiation of wavelength 90 nm is used to ionize, the atom. If the kinetic energy of the ejected electron is 10.4 eV, then the value of n is (hc = 1242 eV nm). Sol: [2] E hc 1242 eV = 13.8 eV 90 K = 10.4 eV = E – K = 13.8 eV – 10.4 eV = 3.4 eV n=2 6. A bullet is fired vertically upwards with velocity v from the surface of a spherical planet. When it reaches its maximum height, its acceleration due to the planet’s gravity is 1/4th of its the value of N is (ignore energy loss due to atmosphere). C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org -4 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) Sol: [2] g g JEE-Advanced-2015 R2 ( R h2 ) 2 1 R2 2 4 R h2 R + h = 2R h=R GMm 1 2 GMm mv R 2 2R 1 2 GMm GMm mv 2 2R R v Vs GM R 2GM V 2 R N=2 7. Two identical uniform discs roll without slipping on two different surface AB and CD (see figure) starting at A and C with linear speeds v1 and v2, respectively, and always remain in contact with the surfaces. If they reach B and D with the same linear speed and v1 = 3 m/s, then v2 in m/s is (g = 10 m/s2). A v1 = 3 m/s 30 m B C v2 27 m D Sol: [7] 1 1 v2 1 2 1 1 1 9 mv mg 30 m 9 mR 2 2 2 2 R 2 2 2 2 R 3 2 27 m mv 30mg 4 4 3 2 27 v 300 4 4 ...(i) 2 3 2 1 1 1 v v 270m mv22 mR 2 22 4 2 2 2 R 3 2 3 v 270 v22 4 4 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org -5 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) 300 30 JEE-Advanced-2015 27 3v 2 270 2 4 4 27 3v22 4 4 147 3v22 4 4 49 v22 v2 = 7 8. Two spherical stars A and B emit blackbody radiation. The radius of A is 400 times that of B and A A emits 104 times the power emitted from B. The ratio of their wavelength A and B at which the B peaks occur in their respective radiation curves is Sol: [2] RA = 400 RB PA = 104 PB P ...(i) E AT 4 t TA4 PA AB PA AB TB4 AA PB PB AA TA4 RB2 4 10 TB4 (400) 2 RB2 TA 1 1 10 TB 20 2 A TB 2 B TA SECTION 2 (Maximum Marks: 40) This section contains TEN questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct. For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS. Marking scheme: + 4 If the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 if none of the bubbles in darkened –2 in all other cases. C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org -6 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) 9. JEE-Advanced-2015 In an aluminium (Al) bar of square cross section, a square hole is drilled and is filled with iron (Fe) as shown in the figure. The electrical resistivities of Al and Fe are 2.7 × 10–8 m and 1.0 × 10–7 m, respectively. The electrical resistance between the two faces P and Q of the composite bar is Q Al Fe 50 mm 2 mm P 7 mm (A) 2475 64 (B) 1875 64 (C) 1875 49 (D) 2475 132 1 1 1 Sol: [B] R R R 1 2 A A 1 1 2 R 1l1 2l2 R1 = 30 × 10–6 R2 = 1250 × 10–6 1 1 1 125 3 64 R 30 1250 3750 1875 R 1875 64 10. For photo-electric effect with incident photon wavelength , the stopping potential is V0. Identify the correct variation (s) of V0 with and 1/. V0 V0 (A) (B) V0 V0 (C) (D) C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org -7 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) Sol: [A, C] JEE-Advanced-2015 Km = E – eV hc eV0 hc hc 0 when = 0 11. Consider a Verner callipers in which each 1 cm on the main scale is divided into 8 equal divisions and a screw gauge with 100 divisions on its circular scale. In the Vernier callipers, 5 divisions of the Vernier scale coincide with 4 divisions on the main scale and in the screw gauge, one complete rotation of the circular scale moves it by two divisions on the linear scale. Then (A) If the pitch of the screw gauge is twice the least count of the Vernier callipers, the least count of the screw gauge is 0.01 mm. (B) If the pitch of the screw gauge is twice the least count of the Vernier callipers, the lest count of the screw gauge is 0.005 mm (C) If the least count of the linear scale of the screw gauge is twice the lest count of the Vernier callipers, the least count of the screw gauge is 0.01 mm (D) If the least count of the linear scale of the screw gauge is twice the least count of the Vernier capillers, the least count of the screw gauge is 0.005 mm. Sol: [B, C] L.C of vernier = 1 msd – 1 vsd = 0.25 mm B. Pitch = 0.5 m L.C C. Pitch 1mm L.C 0.5 0.05 mm 100 1 0.01 mm 100 12. Planck’s constant h, speed of light c and gravitational constant G are used to form a unit of length L and a unit of mass M. Then correct option (s) is (are) (A) M c (B) M G (C) L h (D) L G Sol: [A, C, D] h = [ML2T–1] c = [LT–1] G = [M–1L3T–2] hc M h G M c 1 M 4 Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 C. O.: Ambition, 383, Bank M2 E-mail : [email protected], visit us at : ambitiongroup.org -8 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) L2 hG L5T 3 c 3 L3T 3 JEE-Advanced-2015 L h L G L C 3/2 13. Two independent harmonic oscillators of equal mass are oscillating about the origin with angular frequencies 1 and 2 and have total energies E1 and E2, respectively. The variation of their momenta p with positions x are shown in the figures. If p Energy = E 1 a a n 2 and n , then the correct equation(s) is (are) b R p Energy = E2 b a (A) E11 E2 2 Sol: [B, D] x R 2 2 (B) n 1 x E1 E2 (D) 1 2 (C) 12 n 2 A2 R 1 Amplitudes A a n 1 v2 m R Rn 2 n Maximum speeds v1m b a vm = A 2 vm2 A1 n2 1 vm1 A2 2 1 2 E2 vm2 E 1 E mvm 2 n2 2 1 n 2 2 1 2 E1 vm1 E1 2 n E1 E2 1 2 14. A ring of mass M and radius R is rotating with angular speed about a fixed vertical axis passing through its centre O with two point masses each of mass M/8 at rest at O. These masses can move radially outwards along two massless rods fixed on the ring as shown in the figure. At some instant the O angular speed of the system is 8/9 and one of the masses is at a distance of 3/5R from O. At this instant the distance of the other mass from O is (A) 2 R 3 (B) 1 R 3 (C) 3 R 5 (D) 4 R 5 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org -9 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 Sol: [D] By conservation of angular momentum, MR 2 MR 2 M 8 9R 2 9R 2 x2 R2 8 200 8 x 2 3 M 28 R 5 8 x 9 4 R 5 15. The figures below depict two situations in which two infinitely long static line charges of constant positive line charge density are kept parallel to each other. In their resulting electric field, point charges q and –q are kept in equilibrium between them. The point charges are confined to move in the x direction only. If they are given a small displacement about their equilibrium positions, then the correct statement(s) is(are) x +q –q x (A) Both charges execute simple harmonic motion. (B) Both charges will continue moving in the direction of their displacement (C) Charge +q executes simple harmonic motion while charge –q continues moving in the direction of its displacement. (D) Charge –q executes simple harmonic motion while charge +q continues moving in the direction of its displacement. Sol. [C] Using E 3k r Only positive charge will oscillate. 16. Two identical glass rods S1 and S2 (refractive index = 1.5) have one convex end of radius of curvature 10 cm. They are placed with the curved surfaces at a distance d as shown in the figure, with their axes (shown by the dashed line) aligned. When a point source of light P is placed inside rod S1 on its axis at a distance of 50 cm from the curved face, the light rays emanating from it are found to be parallel to the axis inside S2. The distance d is . S1 S2 P 50 cm (A) 60 cm d (B) 70 cm (C) 80 cm (D) 90 cm C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 10 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 Sol. [B] 1 1.5 1. 1.5 V 50 10 for S1 , V = 50 for S 2 , 0 1 1.5 1 u 10 u = – 20 Therefore, d = 50 + 20 = 70 17. A conductor (shown in the figure) carrying constant current I is kept in the x-y plane in a uniform magnetic field B . If F is the magnitude of the total magnetic force acting on the conductor, then the correct statement (s) is (are) y R R I x L R (A) If B is along zˆ, F ( L R (C) If B is along yˆ, F ( L R ) R L (B) If B is along xˆ, F 0 (D) If B is along zˆ, F 0 Sol. [A, B, C] The conductor can be replaced by a straight conductor. 18. A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in equilibrium at temperature T. Assuming the gases are ideal, the correct statement(s) is (are) (A) The average energy per mole of the gas mixture is 2RT (B) The ratio of speed of sound in the gas mixture to that in helium gas is 6/5 (C) The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1/2 (D) The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1/2 Sol. [A, B, D] A. 5 3 Average K.E. per pole RT RT 2 RT 2 2 B. U mixture U He mixture mixtrue He he mix C pmixture CV mixture C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 11 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) C p mixture Cv mixture 7 5 R R 2 3R 2 2 5 3 R R 2 2R 2 2 Therefore, D. JEE-Advanced-2015 U mixture 3 3 4 6 4 1 2 1 3 because He 4 and mixture He 2 5 5 5 2 1 1 2 mH U M2 mHe U He 2 2 U He mH 2 1 U m 4 2 H He SECTION 3 (Maximum Marks: 16) This section contains TWO questions. Each question contains two columns, Column I and Column II Column I has four entries (A), (B), (C) and (D) Column II has five entries (P), (Q), (R), (S) and (T). Match the entries in Column I with the entries in Column II. One or more entries in Column I may match with one or more entries in Column II. The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below. (A) P Q R S T (B) P Q R S T (C) P Q R S T (D) P Q R S T For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry (A) in Column I matches with entries (Q), (R) and (T) then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D). Marking scheme: For each entry in Column I. + 2 If only the bubble(s) corresponding to all the correct match (es) is (are) darkened. 0 If none of the bubbles is darkened. – 1 In all other cases. C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 12 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 19. Match the nuclear processes given in column I with the appropriate option (s) in column II. Column I Column -II A. Nuclear fusion (P) Absorption of thermal neutrons by B. Fission in a nuclear reactor (Q) C. -decay D. -ray emission 235 92 U 60 27 Co nucleus (R) Energy production in stars via hydrogen conversion to helium (S) Heavy water (T) Neutrino emission Sol. [A-(R); B-(P, S); C-(Q, T); D-(Q)] 20. A particle of unit mass is moving along the x-axis under the influence of a force and its total energy is conserved. Four possible forms of the potential energy of the particle are given in column I (a and U0 are constants). Match the potential energies in column I to the corresponding statement(s) in column II. Column I Column II 2 A. 2 U x U1 ( x ) 0 1 2 a B. U 2 ( x) C. 2 x 2 U0 x U 3 ( x) exp 2 a a D. U 4 ( x) U0 x 2 a U0 2 (P) The force acting on the particle is zero at x = a (Q) The force acting on the particle is zero at x = 0 (R) The force acting on the particle is zero at x = – a. (S) The particle experiences an attractive force towards 2 x 1 x 3 a 3 a x = 0 in the region | x | < a. (T) The particle with total energy U0 can oscillate about 4 the point x = – a Sol. [A-(P),(Q),(R),(T); B-(Q),(S), C-(P),(Q),(R),(S); D-(P),(R),(T)] f dU dx x2 F1 2U o x 1 2 a F2 U0 2x a2 x2 x x3 2 F3 U 0 2 4 e a a a C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 13 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) F4 JEE-Advanced-2015 3x2 U0 1 x2 d 2U 2 3 ( x a ) 1 U 2U 0 1 is positive, therefore U is a 0 1 2 1 2 a a3 and dx 2 a 2 manima. 1 3x 2 d 2U 3 u 2 U 02 is negative therefore is a maxima. 0 2 (at x = –a) dx 2 4 a a a U x d 2U 4 03 is +ve, therefore is a minima. 2 dx a PART II : CHEMISTRY SECTION 1 (Maximum Marks: 32) This section contains EIGHT questions The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive For each question, darken the bubble corresponding to the correct integer in the ORS Marking scheme: + 4 If the bubble corresponding to the answer is darkened 0 in all other cases 21. Not consider the electronic spin, the degeneracy of the second excited state (n = 3) of H atom is 9, while the degeneracy of the second excited state of H+ is Sol: [9] n = 3, l = 0, 1, 2 l = 0, m = 0 l = 1 m = 1–1, 0, + 1 l = 2, m = –2, –1, 0 + 1, +2 For H– degeneracy will be 9 in second excited state 22. All the energy released from the reaction X Y, rG0 = – 193 kJ mol–1 is used for oxidizing M+ as M+ M3+ +2e–, E0 = –0.25V. Under standard conditions, the number of moles of M+ oxidized when one mole of X is converted to Y is [F = 96500 C mol–1] Sol: [4] X Y, G0 = –193 kJ mol–1 As G0 = –nFE0Cell = –2 Ú 96500 × (0.25) J = Total available energy = –193 × 103 J + No. of moles of M oxidised = –193 × 103 ––––––––––––– = 4 –2 × 96500 (0.25) 23. If the freezing point of a 0.01 molal aqueous solution of a cobalt (III) chloride-ammonia complex (which behaves as a strong electrolyte) is –0.0558°C, the number of chloride(s) in the coordination sphere of the complex is [Kf of water = 1.86 K kg mol–1] C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 14 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 Sol: [3] Tf = 0.0538 Kf = 1.86 m = 0.01 As Tf = i × Kf × m i Tf Kf m 1 .8 6 3 0 .0 5 5 8 0 .0 1 Possible structure will be [Co(NH3)3Cl]Cl2 So only one Cl– is within co-ordination sphere. 24. The total number of stereoisomers that can exist for M is CH3 H3 C H3 C M H3C O CH3 Chiral centres Sol: [4] H3C O There are two chiral centres so possible optical isomers = 2 + 2 = 4 No geometrical isomerism is possible 25. The number of resonance structures for N is OH NaOH N Sol: [9] 26. The total number of lone pairs of electrons in N2O3 is Sol: [8] Lone pair = 8 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 15 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 27. For the octahedral complexes of Fe3+ in SCN– (thiocyanato-S) and in CN– ligand environments, the difference between the spin-only magnetic moments in Bohr magnetons (when approximated to the nearest integer) is [Atomic number of Fe = 26] Sol: [2] SCN– is a weak ligand but CN– is a strong ligand. Difference between spin only magnetic movements in B.M. is approximately 2. 28. Among the triatomic molecules/ions, BeCl2, N3 , N2O, NO2 , O3, SCl2, ICl2 , I3 and XeF2, the total number of linear molecule(s)/ion(s) where the hybridization of the central atom does not have contribution from the d-orbital(s) is [Atomic number: S = 16, Cl = 17, I = 53 and Xe = 54] Sol: [4] BeC l 2 , N 3 , N 2 O, NO 2 SECTION 2 (Maximum Marks: 40) This section contains TEN questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct. For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS. Marking scheme: + 4 If the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 if none of the bubbles in darkened –2 in all other cases. 29. The % yield of ammonia as a function of time in the reaction 2NH 3 (g), H 0 at (P, T1) is given below N 2 (g) 3H 2 (g) If this reaction is conducted at (P, T2), and T2 > T1, the % yield of ammonia as a function of time is represented by C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 16 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) (A) (B) (C) (D) JEE-Advanced-2015 Sol. [C] According to Lechatellier Principle formation of Ammonia is formed at high P and low T, as well it is an exothermic process. 30. If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by magnesium ions, m and n, respectively, are (A) 1 1 , 2 8 (B) 1, 1 4 (C) 1 1 , 2 2 (D) 1 1 , 4 8 Sol. [A] 31. Compound(s) that on hydrogenation produce(s) optically inactive compound(s) is(are) Br Br H (A) H3C (B) H2C CH3 H CH3 Br H H2C H CH3 (C) (D) H2C Br CH3 CH3 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 17 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 Sol. [B, D] After hydrogenations H3C (A) will form H3C CH2 (B) H H H C C C H H CH3 Br presence of chiral C make of optically active. H C CH2 Br CH3 No chiral C-atom so optically inactive H H3C CH C (C) H3C Br CH3 Presence of C-carbon make it optically active (D) H3C H H H C C C H Br H CH3 No chiral C-atom optically inactive 32. The major product of the following reaction is O i. KOH , H 2O ii. H , heat CH3 O CH3 CH3 O O (A) (B) O O CH3 CH3 (C) (D) C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 18 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 Sol. [A, D] O O CH3 will first go under aldol condensation then elimination of water will take place. So possible answer (A) and (D) 33. In the following reaction, the major product is CH3 CH2 H2C 1 equivalent HBr CH 3 CH3 CH 3 (A) H 2 C (B) H3C Br Br CH3 CH3 (C) (D) H2C Br Br H3C Sol. [D] 34. The structure of D=(+)-glucose CHO H OH HO H H OH H OH CH 2 OH The structure of L(–)-glucose is CHO HO H (A) CHO H H HO OH HO H HO H CH2 OH (B) H HO CHO CHO OH HO H HO H H HO H HO H HO H OH (C) H HO H CH2 OH OH H CH2 OH (D) H OH CH2 OH Sol. [A] C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 19 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 35. The major product of the reaction is H3C NaNO 2 , aqueous HCl CO 2 H 0 C CH3 H3C NH2 NH2 H3C (A) CH2 OH (B) CH3 OH H3C CH3 CH2 OH OH H3C (C) NH2 (D) CH3 OH CH3 OH O H3C OH Sol. [B] CH3 OH 36. The correct statement(s) about Cr2+ and Mn3+ is(are) [Atomic numbers of Cr = 24 and Mn = 25] (A) Cr2+ is a reducing agent (B) Mn3+ is an oxidizing agent (C) Both Cr2+ and Mn3+ exhibit d4 electronic configuration (D) When Cr2+ is used as a reducing agent, the chromium ion attains d5 electronic configuration Sol. [A, B, C] 37. Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is (are) (A) Impure Cu strip is used as cathode (B) Acidified aqueous CuSO4 is used as electrolyte (C) Pure Cu deposits at cathode (D) Impurities settle as anode-mud Sol. [B, C, D] Factual 38. Fe3+ is reduced to Fe2+ by using (A) H2O2 in presence of NaOH (B) Na2O2 in water (C) H2O2 in presence of H2SO4 (D) Na2O2 in presence of H2SO4 Sol. [C, D] C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 20 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 SECTION 3 (Maximum Marks: 16) This section contains TWO questions. Each question contains two columns, Column I and Column II Column I has four entries (A), (B), (C) and (D) Column II has five entries (P), (Q), (R), (S) and (T). Match the entries in Column I with the entries in Column II. One or more entries in Column I may match with one or more entries in Column II. The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below. (A) P Q R S T (B) P Q R S T (C) P Q R S T (D) P Q R S T For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry (A) in Column I matches with entries (Q), (R) and (T) then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D). Marking scheme: For each entry in Column I. + 2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened. 0 If none of the bubbles is darkened. – 1 In all other cases. 39. Match the anionic species given in Column I that are present in the ore(s) given in Column II. Column I Column II (A) Carbonate (P) Siderite (B) Sulphide (Q) Malachite (C) Hydroxide (R) Bauxite (D) Oxide (S) Calamine (T) Argentite Sol. A–(P), (Q), (S); B–(T); C–(Q), (R); D–(R) C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 21 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 40. Match the thermodynamic process given under Column I with the expressions given under Column II. Column I Column II (A) Freezing of water at 273 K and 1 atm (P) q = 0 (B) Expansion of 1 mol of an ideal gas into a (Q) = 0 vacuum under isolated conditions (R) Ssys < 0 (C) Mixing of equal volumes of two ideal gases at constant temperature and pressure in an isolated container (S) U = 0 (D) Reversible heating of H2(g) at 1 atm from 300 K to 600 K followed by reversible cooling to 300 K at 1 atm (T) G = 0 Sol. A–(R), (T); B–(P), (Q), (S); C–(P), (Q), (S); D–(P), (Q), (S), (T) PART III : MATHEMATICS SECTION 1 (Maximum Marks: 32) This section contains EIGHT questions The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive For each question, darken the bubble corresponding to the correct integer in the ORS Marking scheme: + 4 If the bubble corresponding to the answer is darkened 0 in all other cases x , x 2 41. Let f : be a function defined by f ( x ) , 0, x 2 2 where [x] is the greatest integer less than or equal to x. If I xf ( x 2 ) dx , then the value of 1 2 f ( x 1) (4I – 1) is [ x], x 2 Sol: [0] f (x) = 0, x 2 2 I x f ( x2 ) dx = 2 f ( x 1) 1 2 x f ( x2 ) = dx 2 f ( x 1) 1 2 x f (x2 ) dx 2 f ( x 1) 2 0 0 2 x.0 = 20 1 0 1 2 x f (x ) x f ( x2 ) dx dx 2 f ( x 1) 2 f ( x 1) 0 2 1 x f ( x2 ) dy 2 f ( x 1) 0 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 22 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) 2 = 1 I x .1 dx 2 f ( x 1) 2 1 x2 x dx 2 4 1 JEE-Advanced-2015 2 1 1 [2 1] 4I –1 = 0 4 4 = 42. A cylindrical container is to be made from certain solid material with the following constraints: it has a fixed inner volume of V mm3, has a 2 mm thick solid wall and is open at the top. The bottom of the container is a solid circular disc of thickness 2 mm and is of radius equal to the outer radius of the container. If the volume of the material used to make the container is minimum when the inner radius of the container is 10 mm, then the value of V is 250 Sol: [4] V = r2h M = h[(r + 2)2 – r2] + (l + 2)22 = h(2r + 2) . 2 + 2(r + 2)2 = V (2r + 2) . 2 + 2(r + 2)2 r 2 4 4 = V 2 + 2(r + 2) r r dM 4 8 V 2 3 4( r 2) dr r r when r = 10, we get 8 4 V + 48 = 0 100 1000 V = 1000 H V =4 250 x2 43. Let F ( x) x 6 1 1 2cos 2 t dt for all x and f : 0, 0, be a continuous function. For a 0, , 2 2 if F´(a) + 2 is the area of the region bounded by x = 0, y = 0, y = f(x) and x = a, then f(0) is x2 Sol: [3] Let F(x) = 6 2cos 2 dt x R x 1 and f : 0, [0, ] be a continuous in for a F 2 1 0, 2 , if F´(a) +2 in the area a F´(a) + 2 = f ( x)dx 0 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 23 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 2 Now F´(x) = 2cos2 x 2x – 2cos2x 6 a f ( x)dx 4cos 0 x=a 2 2 a a 2cos a 2 6 2 diff. w.r.t. a 2 2 2 2 f (a) = 4 cos a a.2cos a sin a 2a + 2. 2 cos a sin a 6 6 6 3 f (0) = 4 = 3 4 44. The number of distinct solutions of the equation: 5 cos 2 2 x cos 4 x sin 4 x cos6 x sin 6 x 2 4 in the interval [0, 2] is Sol: [8] 5 cos22x + cos4x + sin4x + sin6x + cos6x = 2 4 5 cos22x + (1 –2 sin2x cos2x) + (1 – 3 sin2x cos2x) = 2 4 5 1 3 cos22x + 1 – sin2x + 1 – sin22x = 2 4 2 4 5 5 cos22x – sin22x =0 4 4 tan22x = 1 2x = 3 5 7 9 11 13 15 , , , , , , , =8 4 4 4 4 4 4 4 4 45. Let the curve C be the mirror image of the parabola y2 = 4x with respect to the line x + y + 4 = 0. If A and B are the points of intersection of C with the line y = –5, then the distance between A and B is Sol: [4] x = 1 intersits y2 = 4x at y = ± 2 so A (1, –2) and B (1, 2) Hence AB = 4 y2 = 4 x (1, –4) (0, –5) y = –5 (1, –5) 46. The minimum number of times a fair coin needs to be tossed, so that the probability of getting at least two heads is at least 0.96, is C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 24 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 Sol: [8] Let the coin be tossed n times. Now p = 1 ,q= 2 n n 1 n 1 1 – C0 C1 0.96 2 2 n 1– (n 1) 0.96 2n n 1 1 0.04 n 2 25 By taking different values of n 8 1 , not true 128 25 9 1 n = 8, , True 256 25 so n = 8 take n = 7, 47. Let n be the number of ways in which 5 boys and 5 girls can stand in a queue in such a way that all the girls stand consecutively in the queue. Let m be the number of ways in which 5 boys and 5 girls can stand in a queue in such a way that exactly four girls stand consecutively in the queue. Then the value of m is n Sol: [5] B1, B2, B3, B4, B5, G1, G2, G3, G4, G5 we take five girls as one unit so n = 6! × 5! we divide 5 girls into two groups of four girls in one unit and one girl in second unit × B1 × B2 × B3 × B4 × B5 × 5! m = 5! × 6C2 × 4! × 2! × 4!.1! m 5! 15 4! 2 5 so n 6! 5! 6 5 = 5 48. If the normals of the parabola y2 = 4x drawn at the end points of its latus rectum are tangents to the circle (x – 3)2 + (y + 2)2 = r2, then the value of r2 is A = (1, 2) dy 2 Sol: [2] y2 = 4x, dx y on A, slope of tan = 1 so equation of normal y –2 = –1 (x –1) x+y–3=0 As it is tangent to (x –3)2 + (y + 2)2 = r2 3 2 3 so r = 2 2 B 2 =2 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 25 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 SECTION 2 (Maximum Marks: 40) This section contains TEN questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct. For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS. Marking scheme: + 4 If the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 if none of the bubbles in darkened –2 in all other cases. 49. Let f ( x ) sin sin sin x for all x and g ( x) sin x for all x . Let ( f g )( x ) denote 2 6 2 f ( g ( x )) and ( g f )( x ) denote g(f(x)). Then which of the following is (are) true ? 1 1 (A) Range of f is , 2 2 (B) Range of f g is 1 , 1 2 2 f ( x) (C) lim x 0 g ( x) 6 (D) There is an x such that ( g f )( x) 1 Sol: [A,B,C] Let f (x) = sin sin sin x for all x R 6 2 g (x) = sin x for all x R 2 (A) Hence sin x 2 2 2 –1 sin sin sin x 1 2 1 1 f ( x) 2 2 (B) (fog) (x) = f (g (x)) = f sin x 2 = sin 6 sin 2 sin 2 sin x – 1 sin 2 sin 2 sin x 1 1 1 Thus fog ( x ) 2 2 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 26 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) sin sin sin x 6 2 lim (C) Also x 0 sin x sin sin x 2 6 2 (D) JEE-Advanced-2015 sin sin x = 6 2 6 sin sin sin x = 1 2 6 2 –sin 30° sin sin sin 6 sin 2 sin x sin 30° so L.H.S. can notbe equal to 1 50. Let PQR be a triangle. Let a QR, b RP and c PQ . If | a | 12, | b | 4 3 and b .c 24 , then which of the following is (are) true ? | c |2 | a | 12 (A) 2 (C) | a b c a | 48 3 | c |2 | a | 30 (B) 2 (D) a.b 72 Sol: [A,C,D] | a | 12,| b | 4 3 and b .c 24 Clearly a b c 0 ; b c a | b |2 | c |2 2b .c | a |2 48 + | c |2 2b .c | a |2 | c |2 48 144 | c |2 48 R a b P c Q | c |2 | a | 24 12 36 2 Also a b c | a |2 | b |2 2(a. b ) | c |2 144 48 2( a.b ) 48 2(a.b ) –144 a.b –72 Also a b a | – a – c | = a c c a so | a b c a | 2(c a ) Also | c a | 2 | c |2 | a |2 | c .a |2 Now = 144 × 48 – 72 × 72 = 72 × 24 = (24)2. 3 Thus | a b c a | 48 3 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 27 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 51. Let X and Y be two arbitrary, 3 × 3, non-zero, skew-symmetric matrices and Z be an arbitrary 3 × 3, non-zero, symmetric matrix. Then which of the following matrices is(are) skew symmetric ? (A) Y3Z4 – Z4Y3 (B) X44 + Y44 (C) X4Z3 – Z3X4 (D) X23 + Y23 Sol. [C,D] X, Y are non-zero skew symmetry matrices and Z is a symmetric matrix So, X´ = –X, Y´ = – Y, Z´ = Z 23 23 23 23 23 23 (X + Y )´ = (X )´ + (Y )´ = (X´) + (Y´) = (–X)23 + (–Y)23 = –(X23 + Y23) (D) (X44 + Y44)´ = (X´)44 + (Y´)44 = X44 + Y44 (B) is wrong Again (Y3Z4 – Z4Y3)´ = (Y3Z4)´ –(Z4Y3)´ = (Z4)´ (Y3)´ – (Y3)´ (Z4)´ = –Z4Y3 – (–Y3) (Z4) = – Z4Y3 + Y3Z4 It is symmetric (A) Now (X4Z3 – Z3X4)´ = (X4Z3)´ –(Z3 X4)´ = (Z3)´ (X4)´ – (X4)´ (Z3)´ = Z3X4 – X4Z3 = – (X4Z3 – Z3X4) Skew symmetric (C) (1 ) 2 52. Which of the following values of a satisfy the equation (2 ) 2 (1 2) 2 (2 2 )2 (1 3) 2 (2 3) 2 648 ? (3 ) 2 (3 2) 2 (3 3)2 (A) –4 (B) 9 (C) –9 (D) 4 Sol. [B,C] (1 )2 (1 2) 2 (1 3) 2 (2 ) 2 (2 2)2 (2 3)2 (3 ) 2 (3 2) 2 (3 3) 2 = – 648 Applying R3 R3 – R2, R2 R2 – R1 L. H. S. = (1 ) 2 (1 2)2 (3 2) (3 4) 5 2 5 4 (1 3)2 (3 6) 5 6 Applying C3 C3 – C2, C2 C2 – C1 L.H.S. (1 ) 2 (2 3) 2(2 5) (3 2) 2 2 (5 2) 2 2 Applying C3 C3 – C2 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 28 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) L.H.S. (1 ) 2 3 2 JEE-Advanced-2015 (2 3) (2 5) 2 2 2 0 0 = 2[42 + 63 – 42 – 103] = – 83 = – 648 (given) 3 = 81 = 9 or – 9 53. In 3 , consider the planes P1 : y = 0 and P2 : x + z = 1. Let P3 be a plane, different from P1 and P2, which passes through the intersection of P1 and P2. If the distance of the point (0, 1, 0) from P3 is 1 and the distance of a point (, , ) from P3 is 2, then which of the following relations is (are) true ? (A) 2 2 2 0 (B) 2 2 4 0 (C) 2 2 10 0 (D) 2 2 8 0 Sol: [B,D] Let plane P3 be P2 + P1 = 0 (x + z –1) + y = 0 x – y + z –1 = 0 1 2 2 1 2 + 2 + 1 = 2 + 2 = 1 2 Thus P3: 2x – y + 2z – 2 = 0 Now 2 2 2 =2 3 2 – + 2 –2 = 6 or –6 2 – + 2 – 8 = 0 (D) or 2 – + 2 + 4 = 0 (B) 54. In 3 , let L be a straight line passing through the origin. the origin. Suppose that all the points on L are at a constant distance from the two planes P1 : x + 2y – z + 1 = 0 and P2 : 2x – y + z – 1 = 0. Let M be the locus of the feet of the perpendiculars drawn from the points on L to the plane P1. Which of the following points lie(s) on M ? 5 2 (A) 0, , 6 3 Sol: [B] 1 1 1 (B) , , 6 3 6 5 1 (C) , 0, 6 6 1 2 (D) , 0, 3 3 x y z a b c | x 2 y z 1| | 2 x y z 1| = 6 6 x + 2y – z + 1 = 2x – y + z –1 x –3y + 2z – z = 0 .....(i) C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 29 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 x y z 3 1 0 x + 2y – z + 1 = –2x + y – z + 1 3x + y = 0 .......(ii) x y z 1 3 2 x 3 y z 0 t1 1 2 1 x = 3 + t1, y = + 2t1, z = –t1 3 + t1 + 2 + 4t1 + t1 + 1 = 0 5 + 6t1 + 1 = 0 1 5 6 1 5 1 5 1 5 x = 3 – y=– ,z= 6 3 6 13 1 1 2 1 5 x= ,y= ,z= 6 3 6 For = 0, we get (B). t1 = 1 1 1 , , 6 3 6 55. Let P and Q be distinct points on the parabola y2 = 2x such that a circle with PQ as diameter passes through the vertex O of the parabola. If P lies in the first quadrant and the area of the triangle OPQ is 3 2 , then which of the following is (are) the coordinates of P ? (A) 4, 2 2 (B) 1 1 (C) , 4 2 9,3 2 (D) 1, 2 Sol. [A,D] 1 2 1 2 P t1 , t1 and Q t2 , t2 2 2 P 1 2 1 2 Circle x t1 x t2 + (y – t1) (y – t2) = 0 2 2 1 22 t1 t2 t1t2 0 4 t1t2 + 4 = 0; t1t2 = –4 O 4 1 8 P t12 , t1 , Q 2 , , O (0, 0) t1 2 t1 1 2 t1 2 8 2 A = t1 0 t1 y2 = 2x Q 1 4 1 t1 0 1 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 30 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) 3 2 JEE-Advanced-2015 1 8 2t1 2 t1 8 2t1 + t = ± 6 2 1 t12 + 4 = ± 3 2t1 t12 3 2t1 4 0 t1 = 2 2, 2 A (4, 2 2 ) and D(1, 2) 56. Let y(x) be a solution of the differential equation (1 + ex)y´ + yex = 1. If y(0) = 2, then which of the following statements is (are) true ? (A) y(–4) = 0 (B) y(–2) = 0 (C) y(x) has a critical point in the interval (–1, 0) (D) y(x) has no critical point in the interval (–1, 0) Sol. [A,D] (1 + en) dy + yen = 1 dx dy ex 1 x dx 1 e 1 e x ex I.F. = 1 e x dx e 1 = e t dt e log t t = ex +1 y . (ex + 1) = 1 1 e x (e x 1) dx c y(ex + 1) = x + c x = 0, y = 2 2×2=0+cc=4 y(ex + 1) = x + 4 y (x) = x4 ex 1 y (–4) = 0, y (–2) 0 y '( x ) (e x 1).1 ( x 4)e x (e x 1)2 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 31 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 Let y(x) = 1 – ex (3 + x) y(0) h (–1) < 0 critical point in (–1, 0) 57. Consider the family of all circles whose centers lie on the straight line y = x. If this family of circles is represented by the differential equation Py´´Qy´1 0 , where P, Q are functions of x, y and y´ (here y´ = dy d2y , y´´ 2 ), then which of the following statemtns is (are) ture ? dx dx (A) P = y + x (B) P = y – x (C) P + Q = 1 – x + y + y´ + (y´)2 (D) P– Q = x + y – y´ – (y´)2 Sol. [B,C] (x –)2 + (y –)2 = r2 2(x –) + 2 (y –) y´= 0 x – + yy´ – y´ = 0 –(y´ + 1) = –x – yy´ = x yy ' y ' 1 ( y ' 1)[1 yy '' ( y ') 2 ] ( x yy ')( y '') = ( y ' 1) 2 0 = y´ + yy´yy´´ + (y´)3 + 1 + yy´´ + (y´)2 – xy´´ – yy´y´´ y´´(y –x) + (y´)3 + (y´)2 + y´ + 1 = 0 y´´(y –x) + y´[(y´)2 + (y´) + 1] + 1 = 0 P = y – x; Q = (y´)2 + y´ + 1 Option (B) and (C) is correct 58. If g : be a differentiable function with g(0) = 0, g´(0) = 0 and g´(1) 0. Let x g ( x), f ( x) | x | 0, x0 x0 and h(x) = e|x| for all x . Let ( f h)( x ) denote f(h(x)) and (h f )( x ) denote h(f(x)). Then which of the following is (are) ture ? (A) f is differentiable at x = 0 (C) (B) h is differentiable at x = 0 f h is differentiable at x = 0 (D) h f is differentiable at x = 0 Sol. [A,D] Lf ´(0) = lim h 0 f ( h) f (0) h (1) g ( h) h 0 h = lim C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 32 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) JEE-Advanced-2015 g ( h) h 0 h So f is diff. at x = 0 (A) Rf ´(0) = lim eh 1 1 h 0 h Again Lf ´(0) lim eh 1 1 h0 h h is non differentiable at x = 0 (B) Rh´(0) = lim g '(1) for x 0 Similarly f ´(h(x)) = g '(1) for x 0 foh is non-differentiable at x = 0 | g ( h) | and Left h 0 h Now for differentiability of (hof) at x = 0 me have right hand derivative = lim hand derivative = lim h 0 | g ( h) | and they are equal as g´(0) = 0 (D) h SECTION 3 (Maximum Marks: 16) This section contains TWO questions. Each question contains two columns, Column I and Column II Column I has four entries (A), (B), (C) and (D) Column II has five entries (P), (Q), (R), (S) and (T). Match the entries in Column I with the entries in Column II. One or more entries in Column I may match with one or more entries in Column II. The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below. (A) P Q R S T (B) P Q R S T (C) P Q R S T (D) P Q R S T For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry (A) in Column I matches with entries (Q), (R) and (T) then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D). Marking scheme: For each entry in Column I. + 2 If only the bubble(s) corresponding to all the correct match (es) is (are) darkened. 0 If none of the bubbles is darkened. – 1 In all other cases. C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 33 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) 59. JEE-Advanced-2015 Column I Column II (A) In 2 , if the magnitude of the projection vector of the vector iˆ ˆj on 3iˆ ˆj is (P) 1 (Q) 2 (R) 3 (S) 4 (T) 5 3 and if 2 3 , then possible values(s) of || is (are) (B) Let a and b be real numbers such that the function 3ax 2 2, x 1 f ( x) 2 bx a , x 1 is differentiable for all x . Then possible value(s) of a is (are) (C) Let 1 be a complex cube root of unity. If (3 3 22 )4 n 3 (2 3 32 )4 n 3 (3 2 32 )4 n 3 0 then possible values(s) of n is (are) (D) Let the harmonic mean of two positive real numbers a and b be 4. If q is a positive real number such that a, 5, q, b is an arithmetic progression, then the value(s) of |q – a| is (are) Sol: [A-(P),(Q); B-(P),(Q); C-(P),(Q,(S),(T); D-(Q),(T)] A. Projection vector of iˆ ˆj on given 3iˆ ˆj (iˆ ˆj ).( 3iˆ ˆj ) 3 3 1 | 3 | 2 3 Also = 2 + So 3 3 2 3 2 3 |4 – 2| = 6 = 2 or –1 || = 2 or 1 Thus A- (P), (Q) B. 3ax 2 2 , x 1 f (x) = 2 , x 1 bx a f(x) is continuous at x = 1 so –3a –2 = b + a2 Also f (x) is diff. at x = 1, so –6a = b So a2 – 6a = –3a –2 a2– 3a + 2 = 0 (a –1) (a –2) = 0 a = 1, 2 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 34 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) C. D. JEE-Advanced-2015 Thus B-(P), (Q) (3 –3 + 22)4n + 3 + (2 + 3 – 32)4n + 3 + (–3 +2 + 32)4n + 3 = 0 8n + 6 (2 + 3 – 32)+ (2 +3 – 32)4n + 3 + 4n+ 3 (2 + 3 – 32) = 0 (8n + 6 + 4n+ 3 + 1) (2 + 3 – 32) = 0 n = 1, 2, 4, 5 are solutions Thus C-(P),(Q),(S),(T) 2ab 4 , a, s, q, b AP ab 2a(15 –2a) = 4a + 4(15 – 2a) b = 15 – 2a 30 a – 4a2 = 4a + 60 – 8a 4a2 – 34a + 60 = 0 2a2 – 17a + 30 = 0 2a2 – 12a – 5a + 30 = 0 (2a – 5) (a – 6) = 0 a = 5/2, a = 6 5 15 , |q – a| = 5 2 2 q = 4, |q –a| = 2 Clearly value of |q –a| are 2 Thus D-(Q),(T) q=5+ 60. Column I Column II (A) In a triangle XYZ, let a, b and c be the lengths of the sides (P) 1 (Q) 2 (R) 3 (S) 5 (T) 6 opposite to the angles X, Y and Z, respectively. If 2(a2 – b2) = c2 sin( X Y ) , then possible values of n for which sin Z cos(n) = 0 is (are) (B) In a triangle XYZ, let a, b and c be the lengths of the sides and opposite to the angles X, Y and Z, respectively. If 1 +cos2X – 2cos2Y = 2sinX sinY, then possible value(s) of a b is (are) (C) In 2 , let 3iˆ ˆj , iˆ 3 ˆj and iˆ (1 ) ˆj be the position vectors of X, Y and Z with respect to the origin O, respectively. If the distance of Z from the bisector of the acute angle of OX 3 with OY is , then possible value(s) of || is are 2 (D) Suppose that F() denotes the area of the region bounded by x = 0, x = 2, y2 = 4x and y = |x – 1| + |x – 2| + ax, where {0,1} . Then the value(s) of F () 8 2 , when 3 = 0 and = 1, is (are) Sol: [A-(P),(R),(S); B-(P); C-(P),(Q); D-(S),(T)] C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 35 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) A. JEE-Advanced-2015 2( a 2 b 2 ) c2 x sin( x y ) sin z b c cos(n) 0 sin x cos y cos x sin y sin z y = a b cos y cos x c c = a cos y b cos x a a 2 c 2 b 2 b c 2 b 2 a 2 . c c c 2ac 2cb = 2a 2 2b 2 1 2c 2 2 z a n cos 0 ( P), ( R) ( S ) B. 2cos2 x 2(2cos 2 y 1) 2sin x sin y 2cos 2 x 4cos 2 y 2 2sin x sin y 4 2sin 2 x 4 4sin 2 y 2sin x sin y 42 sin 2 x sin x 2 2 sin y sin y 2 a2 a b2 b a2 a a 1 9 20 2 &1 2 b b b 2 B-(P) C. The vector along angle bisector is 3iˆ ˆj iˆ 3 ˆj = 2 2 Cleanly the equation of < bisector is y = x 1 Distance = 3 y=3 x=0 2 3–x | | 2 &1 C-(P) and (Q) D. x=2 When = 0 F() = Area between the line y = 3, x = 0, x = 2 C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 36 - Physics, Chemistry & Mathematics (Paper-1) Code-9 (24/05/2015) and y2 = 4x is = 6 F ( ) JEE-Advanced-2015 8 2 3 8 2 6 3 and when = 1 F (1) 8 2 = Area between the lines y = 3 – x, y = x + 1 adn parabola and x = 0 and x = 0 which 3 is = 5. D-(S) and (T) C. O.: Ambition, 383, Bank Street, Munirka, New Delhi - 110067, Tel.: 011-26177182/282, 09818185251 E-mail : [email protected], visit us at : ambitiongroup.org - 37 -
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