2nd MetroNORM Workshop, IST/CTN, Lisbon, 11-12 March 2015 The EMRP IND57 JRP “MetroNORM - Metrology for processing materials with high natural radioactivity” Science • Technology • Impact Franz Josef Maringer Industrial branches affected: • • • • • • • • • Extraction of rare earths Niobium / tantalum ore processing TiO2 pigment production Oil, natural gas and coal industry Phosphate industry - thermal phosphorous, phosphoric acid, phosphate fertilizers Building material & cement industry Water industry, ground water filtration, drinking water production Tin foundries, tin / lead / copper smelting Recycling industry 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 2 © World Nuclear Association Radionuclides affected: 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 3 Problems related to end-user NORM measurements • • • • Big variation of materials / components / matrices Disequilibrium in decay chains Many radionuclides / many gamma peaks in one sample / spectra High level of expertise & instrumentations / technologies required e.g. Ge(HP), alpha spectrometry • Need of fast measurement results for taking fast decisions e.g. compliance of raw material feed in an industrial process • Inclusion of measurement / sampling uncertainties to the compliance decision process e.g. a (± u(a))? < alimit or conservative assessment of a → Bq | Bq/kg | Bq/m³ | Bq/m² 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 4 Metrological challenges in NORM radionuclide metrology • • • • • • • • Decay chains radionuclides of processed NORM are rarely in radioactive equilibrium Some natural radionuclides have no gamma emission or very weak emission probability (e.g. Th-232, U-238, U-234, …) Some radionuclides need alpha spectrometry with sample preparation Inhomogeneity of raw (and sometimes processed) NORM Samples with high Z and very specific elementary composition Monte Carlo simulations (Penelope, Gespecor, GEANT, ETNA, …) are necessary to calculate εp and εt resp. Ksummcoinc Additional to radiometry – element composition analysis is necessary Target relative standard uncertainties of activity values: lower than ±10 % 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 5 EMRP IND57 MetroNORM: scientific and technological objectives JRP period: 1 September 2013 – 31 August 2016 • Development of measurement systems, methods and technique including in-situ systems which support innovative industrial processing of resources containing naturally occurring radioactive material. → total rel. uncertainties lower than 10% (k=1) • Design of traceable measurement procedures (as input to e.g. CEN/ CENELEC standards) for industrial NORM raw material, products, by-products, residues and waste. • Development and establishment of traceable metrological reference materials and standard sources needed for calibration purposes for NORM measurement. → total rel. uncertainties lower than 10% (k=1) 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer Seite 6 EMRP IND57 MetroNORM: scientific and technological objectives • Improvements to decay data for selected natural radionuclides of the 238U, 235U decay chains, and to the rare earth element 138La, focusing on decay chains description and gamma-ray intensities and half-life improvement: – – – – – 238U series: solving of discrepancies in decay scheme data 235U series: improved decay schemes 238U series and 235U series: gamma 232Th series: improved decay schemes 138La: standardisation • Testing of developed systems, standards and reference materials in industrial processing situations. 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer Seite 7 MetroNORM Partners & Network 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 8 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 9 NORM measurement demanded by Council Directive 2013/59/EURATOM • Article 2 SCOPE: …. 2. This directive applies in particular to: …. (c) human activities which involve the presence of natural radiation sources that lead to a significant increase in the exposure of workers or members of the public, in particular: …. (ii) the processing of materials with naturally-occurring radionuclides; (d) the exposure of workers or members of the public to indoor radon, the external exposure from building materials and cases of lasting exposure resulting from the after-effects of an emergency or a past human activity. 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 10 EU Council Directive 2013/59/EURATOM: NORM measurements • Regulatory control (Art. 23 ff) – – – – Notification Exemption from notification Registration / Licensing Release from regulatory control • Occupational exposure (Art. 31 ff) – Workers / classification / individual monitoring - internal exposure – Workplaces / classification / surveillance • • • • Radon in workplaces (Art. 54) RL: 300 Bq/m³ Indoor exposure to radon (Art. 74) Gamma radiation from building materials (Art. 75) Radon action plan (Art. 103) 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 11 ANNEX VII Exemption and clearance criteria as referred to in Articles 24, 26 and 30 E < 1 mSv / year ⇒ 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 12 ANNEX VIII Definition and use of the activity concentration index for the gamma radiation emitted by building materials as referred to in Article 75 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 13 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 14 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 15 The impact of MetroNORM: • • • • • • Improved NORM end-user laboratory / in-situ measurements Metrological traceability of NORM measurements instruments Traceable NORM reference materials and sources Appropriate decay parameters of natural radionuclides Correct evaluation of NORM measurement uncertainties Enhanced quality management for NORM measurements • Improved NMI / DI services for NORM end-users: – instrument calibration – Type approval & legal verification – methods validation (EN ISO/IEC 17025) 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 16 International Committee for Radionuclide Metrology Activites & networking in: • • • • • • • • Aspects of international metrology Measurement standards and reference materials Alpha-particle and beta-particle spectrometry Gamma-ray spectrometry Nuclear decay data Radionuclide metrology in life sciences Source preparation techniques • • • • • • • Intercomparisons Radionuclide metrology techniques Alpha-particle and beta-particle spectrometry Liquid scintillation counting techniques Low-level radioactivity measurement techniques Radionuclide metrology in life sciences Quality assurance and uncertainty evaluation in radioactivity measurements 20th International Conference on Radionuclide Metrology and its Applications BEV & BOKU & TU, Vienna, Austria 8-11 June 2015 http://icrm2015.at 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer 17 2nd Workshop, Lisbon, 11-12 March 2015 F J Maringer Seite 18
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